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What Are Alkanes?

They are any of the series of saturated hydrocarbons including methane, ethane, propane, and higher members.


Here we quickly talk about the reactions they undergo.

First of all, In the absence of a spark or a high-intensity light source, alkanes are generally inert to chemical reactions, meaning, they are not reactive. However, anyone who has used a match to light a gas burner, or dropped a match onto charcoal coated with lighter fluid, should know that alkanes burst into flame in the presence of a spark, meaning, they are combustible. It doesn’t matter whether the starting material is the methane found in natural gas,

CH4(g) + 2 O2(g) ---->CO2(g) + 2 H2O(g)

the mixture of butane and isobutane used in disposable cigarette lighters,

2 C4H10(g) + 13 O2(g) ---->8 CO2(g) + 10 H2O(g)

the mixture of C5 to C6 hydrocarbons in charcoal lighter fluid,

C5H12(g) + 8 O2(g) ---->5 CO2(g) + 6 H2O(g)

or the complex mixture of C6 to C8 hydrocarbons in gasoline.

2 C8H18(l) + 25 O2(g) ----> 16 CO2(g) + 18 H2O(g)

Once the reaction is ignited by a spark, these hydrocarbons burn to form CO2 and H2O and give off between 45 and 50 kJ of energy per gram of fuel consumed.

In the presence of light, or at high temperatures, alkanes react with halogens to form alkyl halides. Reaction with chlorine gives an alkyl chloride.


CH4(g) + Cl2(g) ----> CH3Cl(g) + HCl(g)


Reaction with bromine gives an alkyl bromide.


CH4(g) + Br2(l) ----> CH3Br(g) + HBr(g)



Alkenes And Alkynes

These are two other types of basic hydrocarbons. Alkenes contain less hydrogen, carbon for carbon, than the alkanes. To account for this difference, the carbon atoms are joined by a double bond. The carbon-carbon double bond is the distinguishing feature of the alkene structure.

Unsaturated hydrocarbons such as alkenes and alkynes are much more reactive than the parent alkanes. They react rapidly with bromine, for example, to add a Br2 molecule across the C=C double bond.

This reaction provides a way to test for alkenes or alkynes. Solutions of bromine in CCl4 have an intense red-orange color. When Br2 in CCl4 is mixed with a sample of an alkane, no change is initially observed. When it is mixed with an alkene or alkyne, the color of Br2 rapidly disappears.

The reaction between 2-butene and bromine to form 2, 3-dibromobutane is just one example of the addition reactions of alkenes and alkynes. Hydrogen bromide (HBr) adds across a C=C double bond to form the corresponding alkyl bromide, in which the hydrogen ends up on the carbon atom that had more hydrogen atoms to begin with. Addition of HBr to 2-butene, for example, gives 2-bromobutane.

H2 adds across double (or triple bonds) in the presence of a suitable catalyst to convert an alkene (or alkyne) to the corresponding alkane.

In the presence of an acid catalyst, it is even possible to add a molecule of water across a C=C double bond.

Addition reactions provide a way to add new substituents to a hydrocarbon chain and thereby produce new derivatives of the parent alkanes.

In theory, two products can form when an unsymmetric reagent such as HBr is added to an unsymmetric C=C double bond. In practice, only one product is obtained. When HBr is added to 2-methylpropene, for example, the product is 2-bromo-2-methylpropane, not 1-bromo-2-methylpropane.


In 1870, after careful study of many examples of addition reactions, the Russian chemist Valdimir Markovnikov formulated a rule for predicting the product of these reactions. Markovnikov’s rule states that  the hydrogen atom adds to the carbon atom that already has the larger number of hydrogen atoms when HX adds to an alkene. Thus, water (H OH) adds to propene to form the product in which the OH group is on the middle carbon atom.



Reactions Of Alkanes, Alkenes And Alkynes PDF Download Link